Magkos · Critical reviews in food science and nutrition 2005 · narrative review · n=?

Caffeine use in sports, pharmacokinetics in man, and cellular mechanisms of action.

Cited 344 times in the scientific literature.

Level 5 - mechanism / opinion, no new human data

Narrative review of pharmacokinetics and cellular mechanisms without systematic methodology

PubMed 16371327 · doi:10.1080/1040-830491379245 · record verified 2026-08-27

What was done

This narrative review synthesized evidence on caffeine use in sports, human pharmacokinetic parameters, and cellular mechanisms of action identified across in vitro and in vivo studies.

What was found

Caffeine is rapidly and completely absorbed in the gastrointestinal tract and distributed across all body tissues. Peak plasma concentrations reach approximately 50 microM, and elimination half-lives range from 2.5 to 10 hours. Hepatic microsomes metabolize caffeine into more than 25 derivatives, while less than 5% is excreted unchanged in urine. In vitro mechanisms include potentiation of muscle contractility through sarcoplasmic reticulum calcium release, phosphodiesterase inhibition, glycogen phosphorylase inhibition, sodium/potassium pump stimulation, phosphoinositide metabolism impairment, and non-selective adenosine receptor antagonism. Adenosine receptor blockade is identified as the primary physiologically relevant mechanism accounting for in vivo effects.

Why it matters

The paper outlines the pharmacokinetic profile and cellular actions of caffeine, clarifying the biological basis for its established role as an ergogenic aid in athletic performance.

Limits

As a narrative review, it lacks systematic search criteria, quality appraisal, and meta-analytic synthesis. The abstract provides no sample sizes or count of included studies. Several discussed biochemical actions derive from in vitro experiments that may not reflect physiological conditions in vivo.

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